Carbon dots: synthesis methods, properties and chemical sensing applications
Corressponding author's email:
khoidd@hcmute.edu.vnKeywords:
carbon dots (CDs), top-down method, bottom-up method, fluorescence, chemical sensing, inorganic ions, organic moleculesAbstract
Carbon dots (CDs) are a novel class of fluorescent nanoparticles and carbon nanomaterials with outstanding physical, chemical properties and biocompatibility, which have attracted worldwide attention and have been applied to every branch of applied sciences from the beginning of this millennium. In this article, we have reviewed the recent progress made in this newest member of carbon nanomaterials, focusing on their synthetic strategies namely top-down and bottom-up methods. In addition, their properties including morphology and structure, compositions, optical properties (absorbance, photoluminescence properties, quantum yields and luminescence mechanisms) have been presented. For the applications of this newest member of fluorescent nanoparticles, CDs both with and without being functionalized recognition elements are selective and sensitive for sensing of analytes, including metal ions (e.g., Hg2+, Cu2+, Pb2+), non-metallic ions (e.g. sulfide ions, pyro phosphate ions, sulphite) and small organic molecules (e.g., bisphenol A, dihydroxy benzene, hydroquinone) have been reviewed. Also, the proposed fluorescence sensing mechanism of CDs have been outlined for the explanation of effectively selective and sensitive detections of inorganic ions and small organic molecules of CDs.
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References
G. A. M. Hutton et al., Carbon dots as photosensitisers for solar-driven catalysis, Chem. Soc. Rev., 46(2017) 6111-6123.
J. Wang et al., A review of carbon dots in biological applications, J. Mater. Sci., 51(2016) 4728-4738.
S. Huang et al., Carbon quantum dots: synthesis, properties, and sensing applications as a potential clinical analytical method, Anal. Methods, 11(2019) 2240-2258.
S. N. Baker et al., Luminescent Carbon Nanodots: Emergent Nanolights, Angrew. Chem., Int. Ed., 49(2010) 6726-6744.
J. Geys et al., Acute toxicity and prothrombotic effects of quantum dots: impact of surface charge, Environ. Health Perspect., 116(2008) 1607-1613.
R. Wang et al., Recent progress in carbon quantum dots: synthesis, properties and applications in photocatalysis, J. Mater. Chem. A, 5(2017) 3717-3734.
M. Farshbaf et al., Carbon quantum dots: recent progresses on synthesis, surface modification and applications, Artif Cells Nanomed Biotechnol, 46(2018), 1331-1348.
X. Xu et al., Electrophoretic analysis and purification of fluorescent single-walled carbon nanotube fragments, J. Am. Chem. Soc., 126(2004) 12736-12737.
Y. P. Sun et al., Quantum-sized carbon dots for bright and colorful photoluminescence, J. Am. Chem. Soc., 128(2006) 7756-7757.
L. Cao et al., Carbon dots for multiphoton bioimaging, J. Am. Chem. Soc., 129(2007) 11318-11319.
S. T Yang et al., Carbon dots for optical imaging in vivo, J. Am. Chem. Soc., 131(2009) 11308-11309.
B. Zheng et al., Ultrafast ammonia-driven, microwave-assisted synthesis of nitrogendoped graphene quantum dots and their optical properties, Nanophotonics, (2017) 259- 267.
S. Dey et al., Luminescence properties of boron and nitrogen doped graphene quantum dots prepared from arc-discharge-generated doped graphene samples, Chem. Phys. Lett., 595 -596(2014) 203–208.
S. L. Hu et al., One-step synthesis of fluorescent carbon nanoparticles by laser irradiation, J. Mater. Chem., 19(2009) 484-488.
C. Doñate-Buendia et al., Fabrication by laser irradiation in a continuous flow jet of carbon quantum dots for fluorescence imaging, ACS Omega, 3(2018) 2735-2742.
J. Zhou et al., An electrochemical avenue to blue luminescent nanocrystals from multiwalled carbon nanotubes (MWCNTs), J. Am. Chem. Soc., 129(2007), 744-745.
L. Zheng et al., Electrochemiluminescence of water-soluble carbon nanocrystals released electrochemically from graphite, J. Am. Chem. Soc., 131(2009) 4564-4565.
Z. Zhao et al., Enhanced electrochemical performance of carbon quantum dotspolyaniline hybrid, J. Power Sources, 337(2017) 54-64.
Z. M. Luo et al., Microwave-assisted preparation of white fluorescent graphene quantum dots as a novel phosphor for enhanced white‐light‐emitting diodes, Adv. Funct. Mater. 26 (2016) 2739-2744.
Y. Q. Dong et al., One-step and high yield simultaneous preparation of single- and multi-layer graphene quantum dots from CX-72 carbon black, J. Mater. Chem., 22(2012), 8764 -8766.
R. Q. Ye et al., Coal as an abundant source of graphene quantum dots, Nat. Commun., 4(2013) 2943.
J. Peng et al., Graphene quantum dots derived from carbon fibers, Nano Lett., 12(2012) 844-849.
S. Zhuo et al., Upconversion and downconversion fluorescent graphene quantum dots: ultrasonic preparation and photocatalysis, ACS Nano, 6(2012) 1059-1064.
D. Pan et al., Hydrothermal route for cutting graphene sheets into blue‐luminescent graphene quantum dots, Adv. Mater., 22(2010) 734-738.
L. L. Li et al., A facile microwave avenue to electrochemiluminescent two‐color graphene quantum dots, Adv. Funct. Mater, 22(2012) 2971-2979.
Y. Shin et al., Acid-free and oxone oxidant-assisted solvothermal synthesis of graphene quantum dots using various natural carbon materials as resources, Nanoscale 7(2015) 5633-5637.
C. Zhu et al., A new mild, clean and highly efficient method for the preparation of graphene quantum dots without by-products, J. Mater. Chem. B, 3(2015) 6871-6876.
X. Zhou et al., Photo-fenton reaction of graphene oxide: a new strategy to prepare graphene quantum dots for DNA cleavage, ACS Nano, 6(2012) 6592-6599.
B. C. M. Martindale et al., Solar hydrogen production using carbon quantum dots and a molecular nickel catalyst, J. Am. Chem. Soc., 137(2015) 6018-6025.
M. Chen et al., One-pot green synthesis of water-soluble carbon nanodots with multicolor photoluminescence from polyethylene glycol, J. Mater. Chem. B, 2(2014) 3937-3945.
D. Qu et al., Highly luminescent S, N co-doped graphene quantum dots with broad visible absorption bands for visible light photocatalysts, Nanoscale, 5(2013) 12272- 12277.
F. Yuan et al., Bright multicolor bandgap fluorescent carbon quantum dots for electroluminescent light-emitting diodes, Adv. Mater., 29(2017) 1604436-n/a.
J. Wang et al., A facile large-scale microwave synthesis of highly fluorescent carbon dots from benzenediol isomers, J. Mater. Chem. C, 2(2014) 5028-5035.
F. Du et al., Carbon dots-based fluorescent probes for sensitive and selective detection of iodine, Microchim. Acta 180(2013), 453-460.
Z. Ma et al., One-step ultrasonic synthesis of fluorescent N-doped carbon dots from glucose and their visible-light sensitive photocatalytic ability, New J. Chem., 36(2012) 861-864.
H. T. Li et al., One-step ultrasonic synthesis of water-soluble carbon nanoparticles with excellent photoluminescent properties, Carbon, 49(2011) 605-609.
L. Li et al., A high-yield and versatile method for the synthesis of carbon dots for bioimaging applications, J. Mater. Chem. B, 5(2017) 1935-1942.
B. B. Chen et al., A large-scale synthesis of photoluminescent carbon quantum dots: a self-exothermic reaction driving the formation of the nanocrystalline core at room temperature, Green Chem., 18(2016) 5127-5132.
Y. Li et al., Fast, energy-efficient synthesis of luminescent carbon quantum dots, Green Chem., 16(2014) 2566-2570.
J. Deng et al., Electrochemical synthesis of carbon nanodots directly from alcohols, Chem. Eur. J., 20(2014) 4993-4999.
V. Georgakilas et al., Broad family of carbon nanoallotropes: classification, chemistry, and applications of fullerenes, carbon dots, nanotubes, graphene, nanodiamonds, and combined superstructures, Chem. Rev., 115(2015) 4744-4822.
C. Ding et al., Functional surface engineering of C-dots for fluorescent biosensing and in vivo bioimaging, Acc. Chem. Res., 47(2014) 20–30.
Z. L. Wu et al., Carbon dots: materials, synthesis, properties and approaches to longwavelength and multicolor emission, J. Mater. Chem. B, 5(2017) 3794-3809.
S. Yang et al., Luminescent hollow carbon shells and fullerene-like carbon spheres produced by laser ablation with toluene, J. Mater. Chem., 21(2011) 4432-4436.
S. Hu et al., Controllable synthesis and photoluminescence (PL) of amorphous and crystalline carbon nanoparticles, J. Phys. Chem. Solids, 72(2011) 749-754.
X. Shan et al., B-doped carbon quantum dots as a sensitive fluorescence probe for hydrogen peroxide and glucose detection, Analyst, 139(2014) 2322-2325.
S. Sarkar et al., Amino acid functionalized blue and phosphorous-doped green fluorescent carbon dots as bioimaging probe, RSC Advances, 5(2015) 65913-65921.
S. Chandra et al., Luminescent S-doped carbon dots: an emergent architecture for multimodal applications, J. Mater. Chem. B, 1(2013) 2375-2382.
J. Du et al., Difunctional Cu-doped carbon dots: catalytic activity and fluorescence indication for the reduction reaction of p-nitrophenol, RSC Advances, 7(2017) 33929- 33936.
J. Cheng et al., Zinc ion-doped carbon dots with strong yellow photoluminescence, RSC Advances, 6(2016) 37189-37194.
S. Yang et al., Selenium doped graphene quantum dots as an ultrasensitive redox fuorescent switch, Chem. Mater., 27(2015) 2004-2011.
D. Qu et al., Tailoring color emissions from N-doped graphene quantum dots for bioimaging applications, Light Sci Appl, 4(2015) e364.
R. Jelinek et al., Characterization and physical properties of carbon-dots, carbon quantum dots: synthesis, properties and applications, Springer International Publishing, Cham, 2017, 29-46.
L. Li et al., Focusing on luminescent graphene quantum dots: current status and future perspectives, Nanoscale, 5(2013) 4015-4039.
X. T. Zheng et al., Glowing graphene quantum dots and carbon dots: properties, syntheses, and biological applications, Small, 11(2015) 1620-1636.
S. Li et al., Sulfur-doped graphene quantum dots as a novel fluorescent probe for highly selective and sensitive detection of Fe3+ , Anal. Chem., 86(2014) 10201-10207.
H. Nie et al., Carbon dots with continuously tunable full-color emission and their application in ratiometric pH sensing, Chem. Mater., 26(2014) 3104-3112.
S. T. Yang et al., Carbon dots as nontoxic and high-performance fluorescence imaging agents, J. Phys. Chem. C, 113 (2009) 18110-18114.
X. Zhai et al., Highly luminescent carbon nanodots by microwave-assisted pyrolysis, Chem. Commun., 48(2012) 7955-7957.
H. Zheng et al., Enhancing the luminescence of carbon dots with a reduction pathway, Chem. Commun., 47(2011) 10650-10652.
D. Qu et al., Formation mechanism and optimization of highly luminescent N-doped graphene quantum dots, 4(2014) 5294.
S. Zhu et al., Surface chemistry routes to modulate the photoluminescence of graphene quantum dots: from fluorescence mechanism to up-conversion bioimaging applications, Adv. Funct. Mater, 22(2012) 4732-4740.
Q. Liu et al., Strong two-photon-induced fluorescence from photostable, bio- compatible nitrogen-doped graphene quantum dots for cellular and deep-tissue imaging, Nano Lett., 13(2013) 2436-2441.
Z. Wang et al., Graphene quantum dots: versatile photoluminescence for energy, biomedical, and environmental applications, Journal of Materials Chemistry C, 3(2015) 1157 -1165.
S. Hu et al., Tunable photoluminescence across the entire visible spectrum from carbon dots excited by white light, Angew. Chem. Int. Ed., 54(2015) 2970-2974.
H. Ding et al., Full-color light-emitting carbon dots with a surface- state-controlled lumi- nescence mechanism, ACS Nano, 10(2016) 484-491.
A. Suryawanshi et al., Large scale synthesis of graphene quantum dots (GQDs) from waste biomass and their use as an efficient and selective photoluminescence on-off-on probe for Ag+ ions, Nanoscale, 6(2014) 11664-11670.
T. Yang et al., Nitrogen and sulfur codoped graphene quantum dots as a new fluorescent probe for Au3+ ions in aqueous media, RSC Adv., 5(2015) 107340-107347.
B. Shi etal., One-pot green synthesis of oxygen-rich nitrogen-doped graphene quantum dots and their potential application in pH-sensitive photoluminescence and detection of mercury(II) ions, Talanta, 142(2015) 131-139.
F. Wang et al., Graphene quantum dots as a fluorescent sensing platform for highly efficient detection of copper(II) ions, Sens. Actuators B Chem., 190(2014) 516-522.
S. Huang et al., Graphene quantum dots as on-off-on fluorescent probes for chromium(VI) and ascorbic acid, Microchim. Acta, 182(2015) 1723-1731.
L. Zhang et al., Nitrogen-doped graphene quantum dots as a new catalyst accelerating the coordination reaction between cadmium(II) and 5,10,15,20-Tetrakis(1-methyl -4- pyridinio) porphyrin for cadmium(II) sensing, Anal. Chem., 87(2015) 10894-10901.
Y. X. Qi et al., Highly sensitive and selective fluorescent detection of cerebral lead(II) based on graphene quantum dot conjugates, Chem. Commun., 49(2013) 10599-10601.
H. Huang et al., The electron-transfer based interaction between transition metal ions and photoluminescent graphene quantum dots (GQDs): a platform for metal ion sensing, Talanta, 117(2013) 152-157.
N. Yu et al., Graphene quantum dots combined with copper(II) ions as a fluorescent probe for turn-on detection of sulfide ions, Microchim. Acta, 182(2015) 2139-2146.
L. Lin et al., One-pot synthesis of highly greenish-yellow fluorescent nitrogen-doped graphene quantum dots for pyrophosphate sensing via competitive coordination with Eu3+ ions, Nanoscale, 7(2015) 15427-15433.
S. Chen et al., A facile photoluminescence modulated nanosensor based on nitrogendoped graphene quantum dots for sulfite detection, New J. Chem., 39(2015) 8114-8120.
J. J. Liu et al., Graphene quantum dots-based fluorescent probe for turn-on sensing of ascorbic acid, Sens. Actuators B Chem., 212(2015) 214-219.
H. Huang et al., Highly sensitive detection of bisphenol A in food packaging based on graphene quantum dots and peroxidase, Anal. Methods, 7(2015) 2928-2935.
Y. Li et al., Highly sensitive fluorescent detection of dihydroxybenzene based on graphene quantum dots, Sens. Actuators B Chem., 205(2014) 227-233.
Y. He et al., Graphene quantum dots: highly active bifunctional nanoprobes for nonenzymatic photoluminescence detection of hydroquinone, Biosens. Bioelectron., 74(2015) 418 -422.
L. Fan et al., Fluorescence resonance energy transfer quenching at the surface of graphene quantum dots for ultrasensitive detection of TNT, Talanta, 101(2012) 192-197.
L. Lin et al, A facile synthesis of highly luminescent nitrogen-doped graphene quantum dots for the detection of 2,4,6-trinitrophenol in aqueous solution, Nanoscale, 7(2015) 1872-1878.
J. J. Liu et al., Glutathione-functionalized graphene quantum dots as selective fluorescent probes for phosphate-containing metabolites, Nanoscale, 5(2013) 1810- 1815.
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