Degradation of Tetracycline by Composite Catalyst Derived from Food Waste and Goethite
Corressponding author's email:
anhttk@hcmute.edu.vnDOI:
https://doi.org/10.54644/jte.2024.1592Keywords:
Advanced oxidation processes, Adsorption, Tetracycline removal, Soybean curd, GoethiteAbstract
Current studies on the removal of emerging contaminants (such as pharmaceuticals, personal care products, and their metabolites) from environmental matrices have received a lot of interest due to their adverse impacts on human health and ecology. Among these emerging contaminants, Tetracycline hydrochloride (TCH) - has become a common antibiotic prominent found in hospital and municipal wastewater. The present research develops soybean curd biochar loading goethite (SBCG) and soybean curd activated carbon loading goethite (SACG), a magnetic material made from soybean curd residue and Fe precursor (α-FeOOH), for advanced oxidation processes (AOPs) of TCH in aqueous solutions. Soybean curd biochar loading goethite and soybean curd activated carbon loading goethite demonstrated decomposition performances of 82.8% and 95.3% for the oxidizing agent H2O2 at pH 2, and 87.2% and 94.8% for the oxidizing agent K2S2O8 at pH 7, respectively. Furthermore, the oxidant utilized in the reaction was more H2O2 than K2S2O8. In which the initial concentration was 70 mM H2O2 and 20 mM K2S2O8, the residual concentration after the reaction was 19 - 22 mM H2O2 and 6.5 – 9.35 mM K2S2O8 for SACG and SBCG. The consumption of H2O2 and K2S2O8 per unit treatment agent for SACG material with an initial TCH concentration of 300 mg/L was 75.5 and 20mmol oxidant/mmol TCH, respectively. This demonstrates that combining K2S2O8 with SACG produces the most beneficial outcomes, such as saving time, chemicals, and the amount of post-treated water with a neutral pH value.
Downloads: 0
References
K. Samal, S. Mahapatra, and M. H. Ali, "Pharmaceutical wastewater as emerging contaminants (EC): Treatment technologies, impact on environment and human health," Energy Nexus, vol. 6, p. 100076, 2022. DOI: https://doi.org/10.1016/j.nexus.2022.100076
M. Tannoury and Z. Attieh, "The influence of emerging markets on the pharmaceutical industry," Current Therapeutic Research, vol. 86, pp. 19-22, 2017. DOI: https://doi.org/10.1016/j.curtheres.2017.04.005
T. Cherian, C. Ragavendran, S. Vijayan, S. Kurien, and W. J. G. M. Peijnenburg, "A review on the fate, human health and environmental impacts, as well as regulation of antibiotics used in aquaculture," Environmental Advances, p. 100411, 2023. DOI: https://doi.org/10.1016/j.envadv.2023.100411
Y. Dai et al., "A review on pollution situation and treatment methods of tetracycline in groundwater," Separation Science and Technology, vol. 55, no. 5, pp. 1005-1021, 2020. DOI: https://doi.org/10.1080/01496395.2019.1577445
L. Wang et al., "Degradation of tetracycline hydrochloride (TCH) by active photocatalyst rich in oxygen vacancies: Performance, transformation product and mechanism," Applied Surface Science, vol. 589, p. 152902, 2022. DOI: https://doi.org/10.1016/j.apsusc.2022.152902
X. Peng, J. Cao, B. Xie, M. Duan, and J. Zhao, "Evaluation of degradation behavior over tetracycline hydrochloride by microbial electrochemical technology: Performance, kinetics, and microbial communities," Ecotoxicology and Environmental Safety, vol. 188, p. 109869, 2020. DOI: https://doi.org/10.1016/j.ecoenv.2019.109869
Q. Li et al., "Catalytic degradation of antibiotic by Co nanoparticles encapsulated in nitrogen-doped nanocarbon derived from Co-MOF for promoted peroxymonosulfate activation," Chemical Engineering Journal, vol. 429, p. 132269, 2022. DOI: https://doi.org/10.1016/j.cej.2021.132269
J. Ye, M. Zhou, Y. Le, B. Cheng, and J. Yu, "Three-dimensional carbon foam supported MnO2/Pt for rapid capture and catalytic oxidation of formaldehyde at room temperature," Applied Catalysis B: Environmental, vol. 267, p. 118689, 2020. DOI: https://doi.org/10.1016/j.apcatb.2020.118689
Z. Zhang et al., "Effective and structure-controlled adsorption of tetracycline hydrochloride from aqueous solution by using Fe-based metal-organic frameworks," Applied Surface Science, vol. 542, p. 148662, 2021. DOI: https://doi.org/10.1016/j.apsusc.2020.148662
A. J. Sayyed, D. V. Pinjari, S. H. Sonawane, B. A. Bhanvase, J. Sheikh, and M. Sillanpää, "Cellulose-based nanomaterials for water and wastewater treatments: A review," Journal of Environmental Chemical Engineering, vol. 9, no. 6, p. 106626, 2021. DOI: https://doi.org/10.1016/j.jece.2021.106626
S. O. Ganiyu, S. Sable, and M. G. El-Din, "Advanced oxidation processes for the degradation of dissolved organics in produced water: A review of process performance, degradation kinetics and pathway," Chemical Engineering Journal, vol. 429, p. 132492, 2022. DOI: https://doi.org/10.1016/j.cej.2021.132492
T. Yu, H. Chen, T. Hu, J. Feng, W. Xing, L. Tang, and W. Tang, "Recent advances in the applications of encapsulated transition-metal nanoparticles in advanced oxidation processes for degradation of organic pollutants: A critical review," Applied Catalysis B: Environmental, vol. 342, p. 123401, 2024. DOI: https://doi.org/10.1016/j.apcatb.2023.123401
Y. Guo et al., "Goethite/biochar-activated peroxymonosulfate enhances tetracycline degradation: Inherent roles of radical and non-radical processes," Science of The Total Environment, vol. 783, p. 147102, 2021. DOI: https://doi.org/10.1016/j.scitotenv.2021.147102
J. Liu, C. Peng, and X. Shi, "Preparation, characterization, and applications of Fe-based catalysts in advanced oxidation processes for organics removal: A review," Environmental Pollution, vol. 293, p. 118565, 2022. DOI: https://doi.org/10.1016/j.envpol.2021.118565
M. O. Akharame et al., "Beta-FeOOH nanoparticles: A promising nano-based material for water treatment and remediation," Journal of Nanoparticle Research, vol. 23, pp. 1-33, 2021. DOI: https://doi.org/10.1007/s11051-020-05117-w
T. T. Loc, N. D. Dat, and H. N. Tran, "Nano-sized hematite-assembled carbon spheres for effectively adsorbing paracetamol in water: Important role of iron," Korean Journal of Chemical Engineering, vol. 40, no. 12, pp. 3029-3038, 2023. DOI: https://doi.org/10.1007/s11814-021-1013-z
P. T. T. Ninh, N. D. Dat, M. L. Nguyen, N. T. Dong, H. P. Chao, and H. N. Tran, "Two-stage preparation of highly mesoporous carbon for super-adsorption of paracetamol and tetracycline in water: Important contribution of pore filling and π-π interaction," Environmental Research, vol. 218, p. 114927, 2023. DOI: https://doi.org/10.1016/j.envres.2022.114927
R. T. Rasheed, H. S. Mansoor, and R. R. Al-Shaikhly, "Preparation and a new method to determinate catalase mimics activity of MnO2, Fe2O3 and MnO2: Fe2O3," in AIP Conference Proceedings, AIP Publishing, 2020. DOI: https://doi.org/10.1063/5.0000451
Y. Liu et al., "Current analytical methods for the determination of persulfate in aqueous solutions: A historical review," Chemical Engineering Journal, vol. 416, p. 129143, 2021. DOI: https://doi.org/10.1016/j.cej.2021.129143
M. R. C. Díaz, E. C. López, A. C. Naranjo, and M. L. R. Cervantes, "On the textural and crystalline properties of Fe-carbon xerogels. Application as Fenton-like catalysts in the oxidation of paracetamol by H2O2," Microporous and Mesoporous Materials, vol. 237, pp. 282-293, 2017. DOI: https://doi.org/10.1016/j.micromeso.2016.09.035
A. A. Babaei and F. Ghanbari, "COD removal from petrochemical wastewater by UV/hydrogen peroxide, UV/persulfate and UV/percarbonate: Biodegradability improvement and cost evaluation," Journal of Water Reuse and Desalination, vol. 6, no. 4, pp. 484-494, 2016. DOI: https://doi.org/10.2166/wrd.2016.188
Y. Yang, P. Wang, S. Shi, and Y. Liu, "Microwave enhanced Fenton-like process for the treatment of high concentration pharmaceutical wastewater," Journal of Hazardous Materials, vol. 168, no. 1, pp. 238-245, 2009. DOI: https://doi.org/10.1016/j.jhazmat.2009.02.038
G. V. Buxton, C. L. Greenstock, W. P. Helman, and A. B. Ross, "Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (⋅OH/⋅O− in aqueous solution," Journal of Physical and Chemical Reference Data, vol. 17, no. 2, pp. 513-886, 1988. DOI: https://doi.org/10.1063/1.555805
N. B. Bermúdez, M. G. Avendaño, I. L. Touriño, A. C. Naranjo, and M. L. R. Cervantes, "Fe-Cu doped multiwalled carbon nanotubes for Fenton-like degradation of paracetamol under mild conditions," Nanomaterials, vol. 10, no. 4, p. 749, 2020. DOI: https://doi.org/10.3390/nano10040749
S. Zong, X. Xu, G. Ran, and J. Liu, "Comparative study of atrazine degradation by magnetic clay activated persulfate and H2O2," RSC Advances, vol. 10, no. 19, pp. 11410-11417, 2020. DOI: https://doi.org/10.1039/D0RA00345J
Downloads
Published
How to Cite
License
Copyright (c) 2024 Journal of Technical Education Science
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
Copyright © JTE.
