Synthesis of Cu/TiO2 nanocomposite by gamma irradiation for enhanced photocatalytic activity

Các tác giả

  • Thị Thu Như Võ Ho Chi Minh City University of Technology and Education, Vietnam
  • Văn Hiền Chư Trường Đại học Sư phạm Kỹ thuật Tp.Hồ Chí Minh, Việt Nam

Email tác giả liên hệ:

nhuvtt@hcmute.edu.vn

Từ khóa:

TiO2, copper, nanoparticles, photocatalytic, irradiation, rhodamine B

Tóm tắt

TiO2 doped with copper nanoparticles (Cu/TiO2) was prepared by g-irradiation method. The Cu/TiO2 nanoparticles were characterized using X-ray diffraction, transmission electron microscopy (TEM) and diffuse reflectance spectra (DRS). The photo-catalytic degradation of rhodamine B (RB) in the aqueous suspensions of TiO2 and Cu/TiO2 under visible light was carried out. Results showed that Cu/TiO2 catalysts was found to enhance photo-degradation efficiency of rhodamine B compared to pure TiO2.At 3.0% Cu content, the Cu/TiO2 photocatalyst exhibited the highest visible light photocatalytic activity. The higher activity of copper doped TiO2 is due to the enhancement of electron-hole separation by the electron trapping of copper particles.

Tải xuống: 0

Dữ liệu tải xuống chưa có sẵn.

Tài liệu tham khảo

A. D. Paola, G. Cufalo, M. Addamo, M. Bellardita, R. Camopostrini, M. Ischia, R. Ceccato, L. Palmisano, Photocatalytic activity of nanocrystalline TiO2 (brookite, rutile and brookite-based) powders prepared by thermohydrolysis of TiCl4 in aqueous chloride solutions, Colloids and Surfaces A: Physicochemical and Engineering Aspects. 317 (2008) 366-376.

M. R. Hoffmann, S. T. Martin, W. Choi, D. W. Bahnemann, Environmental applications of semiconductor photocatalysis, Chemical reviews. 95 (1995) 69-96.

A. Emeline, G. Kataeva, V. Ryabchuk, N. Serpone, Photostimulated generation of defects and surface reactions on a series of wide band gap metal-oxide solids, The Journal of Physical Chemistry B. 103 (1999) 9190-9199.

C. T. Hsieh, W. S. Fan, W. Y. Chen, J. Y. Lin, Adsorption and visible-light-derived photocatalytic kinetics of organic dye on Co-doped titania nanotubes prepared by hydrothermal synthesis, Separation and Purification Technology. 67 (2009) 312-318.

M. Atashfaraz, M. S. Niassar, S. Ohara, K. Minami, M. Umetsu, T. Naka, T. Adschiri, Effect of titanium dioxide solubility on the formation of BaTiO3 nanoparticles in supercritical water, Fluid Phase Equilibria. 257 (2007) 233-237.

K. J. Zhang, X. Wei, X. J. Li, S. J. Zheng, X. Gang, J.H. Wang, Photocatalytic oxidation activity of titanium dioxide film enhanced by Mn non-uniform doping, Transactions of Nonferrous Metals Society of China. 16 (2006) 1069-1075.

M. Wang, G. Song, J. Li, L. Miao, B. Zhang, Direct hydrothermal synthesis and magnetic property of titanate nanotubes doped magnetic metal ions, Journal of University of Science and Technology Beijing. 15 (2008) 644-648.

R. F. Chen, C. X. Zhang, J. Deng, G. Q. Song, Preparation and photocatalytic activity of Cu2+ -doped TiO2/SiO2, International Journal of Minerals, Metallurgy and Materials. 16 (2009) 220-225.

J. C. Xu, M. Lu, X. Y. Guo, H. L. Li, Zinc ions surface-doped titanium dioxide nanotubes and its photocatalysis activity for degradation of methyl orange in water, Journal of Molecular Catalysis A: Chemical. 226 (2005) 123-127.

D. Dvoranova, V. Brezova, M. Mazúr, M. A. Malati, Investigations of metal-doped titanium dioxide photocatalysts, Applied Catalysis B: Environmental. 37 (2002) 91-105.

J. Zhu et al., Hydrothermal doping method for preparation of Cr3+-TiO2 photocatalysts with concentration gradient distribution of Cr3+, Applied Catalysis B: Environmental. 62 (2006) 329-335.

G. Wu, T. Nishikawa, B. Ohtani, A. Chen, Synthesis and characterization of carbon-doped TiO2 nanostructures with enhanced visible light response, Chemistry of Materials. 19 (2007) 4530-4537.

K. Patil, S. Sathaye, Y. Khollam, S. Deshpande, N. Pawaskar, A. Mandale, Preparation of TiO2 thin films by modified spin-coating method using an aqueous precursor, Materials letters. 57 (2003) 1775-1780.

J. Belloni, M. Mostafavi, H. Remita, J.L. Marignier, and M.O. Delcourt, Radiation-induced synthesis of mono-and multi-metallic clusters and nanocolloids, New Journal of Chemistry. 22 (1998) 1239-1255.

H. Remita, I. Lampre, M. Mostafavi, E. Balanzat, S. Bouffard, Comparative study of metal clusters induced in aqueous solutions by γ-rays, electron or ion beam irradiation, Radiation Physics and chemistry. 72 (2005) 575-586.

P. V. Viet, T. T. Sang, N. Q. Hien, C. M. Thi, Synthesis of a silver/TiO2 nanotube nanocomposite by gamma irradiation for enhanced photocatalytic activity under sunlight, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms. 429 (2018) 14-18.

Tải xuống

Đã Xuất bản

2020-02-26

Cách trích dẫn

[1]
. T. T. N. Võ và V. H. Chư, “Synthesis of Cu/TiO2 nanocomposite by gamma irradiation for enhanced photocatalytic activity”, JTE, vol 15, số p.h 1, tr 36–40, tháng 2 2020.