Fabrication of a Superhydrophobic RGO Coated-Polyurethan Sponge for Removing Oil, Organic Solvent, and Gasoline from Water
Email tác giả liên hệ:
nhungntp@pvu.edu.vnDOI:
https://doi.org/10.54644/jte.2024.1573Từ khóa:
Oil/water separation, Superhydrophobic sponge, Reduced graphene, Superoleophilic, HDPETóm tắt
In recent years, the issue of oil and organic spillage caused by human population growth has become increasingly urgent, not only in Vietnam but also worldwide. Researchers are showing great interest in the research and development of materials capable of selectively absorbing oils and organic solvents while repelling water. In this project, an oil-absorbing material was developed using reduced graphene oxide particles incorporated into a polyurethane (PU) foam base. Utilizing PU sponge as the base material enhances the oil absorption capacity of the material. Graphene oxide was initially synthesized using the Hummers method and then reduced with ascorbic acid to form reduced graphene oxide (RGO). RGO was applied to the sponge with varying loading amounts, ranging from 0 to 254%. Subsequently, the porous material was coated with high-density polyethylene (HDPE) to assess its hydrophobicity and its ability to adsorb oil and organic solvents. The results indicate that the oil and organic solvent absorption capacity of RGO and HDPE coating materials is highest at RGO loading percentages exceeding 64%, yielding absorption rates ranging from 35 to 63 times the weight of the material. Additionally, the contact angle of RGO and HDPE coating materials is approximately 150°, demonstrating the high hydrophobicity of the material.
Tải xuống: 0
Tài liệu tham khảo
T. Iline-Vul et al., “Engineering of superhydrophobic silica microparticles and thin coatings on polymeric films by ultrasound irradiation,” Mater. Today Chem., vol. 21, Aug. 2021, doi: 10.1016/j.mtchem.2021.100520. DOI: https://doi.org/10.1016/j.mtchem.2021.100520
J. T. Simpson, S. R. Hunter, and T. Aytug, “Superhydrophobic materials and coatings: A review,” Reports Prog. Phys., vol. 78, no. 8, p. 86501, 2015, doi: 10.1088/0034-4885/78/8/086501. DOI: https://doi.org/10.1088/0034-4885/78/8/086501
E. C. Cho et al., “Robust multifunctional superhydrophobic coatings with enhanced water/oil separation, self-cleaning, anti-corrosion, and anti-biological adhesion,” Chem. Eng. J., vol. 314, pp. 347–357, 2017, doi: 10.1016/j.cej.2016.11.145. DOI: https://doi.org/10.1016/j.cej.2016.11.145
T. Phuong, N. Nguyen, T. V. Nguyen, and P. A. Nguyen, “Micro and nanostructured ZnO-based superhydrophobic steel surface with enhanced corrosion protection.”
T. P. N. Nguyen, T. N. T. Nguyen, H. L. Nguyen, T. H. Tran, V. K. Nguyen, and P. A. Nguyen, “Micro/nanostructured ZnO-based superhydrophobic steel surface with enhanced corrosion protection,” Petrovietnam J., vol. 6, pp. 59–66, 2022, doi: 10.47800/pvj.2022.06-07. DOI: https://doi.org/10.47800/PVJ.2022.06-07
Z. Wang, L. Zhu, H. Liu, and W. Li, “A conversion coating on carbon steel with good anti-wax performance in crude oil,” J. Pet. Sci. Eng., vol. 112, pp. 266–272, 2013, doi: 10.1016/j.petrol.2013.11.013. DOI: https://doi.org/10.1016/j.petrol.2013.11.013
S. Yu and H. Li, “Fabrication of superhydrophobic and oleophobic zinc coating on steel surface,” Mater. Sci. Technol. (United Kingdom), vol. 33, no. 11, pp. 1290–1297, 2017, doi: 10.1080/02670836.2017.1288675. DOI: https://doi.org/10.1080/02670836.2017.1288675
J. Zimmermann, F. A. Reifler, U. Schrade, G. R. J. Artus, and S. Seeger, “Long term environmental durability of a superhydrophobic silicone nanofilament coating,” Colloids Surfaces A Physicochem. Eng. Asp., vol. 302, no. 1–3, pp. 234–240, Jul. 2007, doi: 10.1016/j.colsurfa.2007.02.033. DOI: https://doi.org/10.1016/j.colsurfa.2007.02.033
A. K. Kota, G. Kwon, and A. Tuteja, “The design and applications of superomniphobic surfaces,” NPG Asia Mater., vol. 6, no. 6, pp. 1–16, 2014, doi: 10.1038/am.2014.34. DOI: https://doi.org/10.1038/am.2014.34
J. Huang, M. Yang, H. Zhang, and J. Zhu, “Solvent-Free Fabrication of Robust Superhydrophobic Powder Coatings,” ACS Appl. Mater. Interfaces, vol. 13, no. 1, pp. 1323–1332, Jan. 2021, doi: 10.1021/acsami.0c16582. DOI: https://doi.org/10.1021/acsami.0c16582
N. T. Duc, N. T. Tung, N. T. Mien, P. Thi, T. Ha, and N. V. Khoi, “Oil-absorbent Materials from graft copolymer of bamboo fiber and alkyl acrylates,” (in Vietnamese), vol. 2, no. 1, pp. 10–14, 2015.
S. Gupta and N. H. Tai, “Carbon materials as oil sorbents: A review on the synthesis and performance,” J. Mater. Chem. A, vol. 4, no. 5, pp. 1550–1565, 2016, doi: 10.1039/c5ta08321d. DOI: https://doi.org/10.1039/C5TA08321D
C. F. Wang and S. J. Lin, “Robust Superhydrophobic/superoleophilic sponge for effective continuous absorption and expulsion of oil pollutants from Water,” ACS Appl. Mater. Interfaces, vol. 5, no. 18, pp. 8861–8864, 2013, doi: 10.1021/am403266v. DOI: https://doi.org/10.1021/am403266v
Y. Luo, S. Jiang, Q. Xiao, C. Chen, and B. Li, “Highly reusable and superhydrophobic spongy graphene aerogels for efficient oil/water separation,” Sci. Rep., vol. 7, no. 1, pp. 1–10, 2017, doi: 10.1038/s41598-017-07583-0. DOI: https://doi.org/10.1038/s41598-017-07583-0
S. Pei and H. M. Cheng, “The reduction of graphene oxide,” Carbon N. Y., vol. 50, no. 9, pp. 3210–3228, 2012, doi: 10.1016/j.carbon.2011.11.010. DOI: https://doi.org/10.1016/j.carbon.2011.11.010
B. Li, X. Liu, X. Zhang, W. Chai, Y. Ma, and J. Tao, “Facile preparation of graphene-coated polyurethane sponge with superhydrophobic/superoleophilic properties,” J. Polym. Res., vol. 22, no. 10, 2015, doi: 10.1007/s10965-015-0832-1. DOI: https://doi.org/10.1007/s10965-015-0832-1
Tải xuống
Đã Xuất bản
Cách trích dẫn
Số
Chuyên mục
Categories
Giấy phép
Bản quyền (c) 2024 Tạp chí Khoa học Giáo dục Kỹ Thuật
Tác phẩm này được cấp phép theo Giấy phép quốc tế Creative Commons Attribution-NonCommercial 4.0 .
Bản quyền thuộc về JTE.


