Synthesis and Characterization of Oxidized Starch-Montmorillonite Composite for Efficient Removal of Crystal Violet Dye from Aqueous Solutions

Các tác giả

Email tác giả liên hệ:

nguyenvanhung.case@gmail.com

DOI:

https://doi.org/10.54644/jte.2024.1730

Từ khóa:

Montmorillonite, Adsorbent, Oxidized starch, Crystal violet, Water treatment

Tóm tắt

An effective adsorbent was synthesized by modifying Montmorillonite (MMT) clay with oxidized starch, aiming to remove crystal violet (CV) dye from aqueous solutions. The chemical modifications in the MMT-oxidized starch composite were characterized using Fourier-transform infrared spectroscopy (FTIR), confirming the successful integration of oxidized starch with MMT. The adsorption performance was evaluated under varying conditions, including initial dye concentration, adsorbent dosage, pH, and contact time. Kinetic analysis revealed that the adsorption process followed a pseudo-second-order model, while equilibrium data were fitted by the Langmuir isotherm, indicating monolayer adsorption. The adsorbent demonstrated a high adsorption capacity of 25.4 mg/g at pH 7 for CV dye. Thermogravimetric analysis (TGA) confirmed the thermal stability of the synthesized material and these findings suggest that oxidized starch-MMT is a promising alternative for the efficient removal of cationic dyes like crystal violet from wastewater, with significant implications for scalable water treatment applications and broader environmental remediation efforts in both industrial and municipal settings.

Tải xuống: 0

Dữ liệu tải xuống chưa có sẵn.

Tiểu sử của Tác giả

Van Hung Nguyen, Graduate University of Science and Technology (GUST), Vietnam Academy of Science and Technology (VAST), Vietnam

Nguyen Van Hung obtained Master’s degree from University of Science and is a PhD student at Graduate University of Science and Technology, Vietnam Academy of Science and Technology. His research focuses on the synthesis of new materials for environmental treament and analysis applications and develop new analytical methods for application in the food field. Email: nguyenvanhung.case@gmail.com. ORCID:  https://orcid.org/0009-0006-8754-1249

Dang Khoa Vo Nguyen, Institute of Applied Materials Science (IAMS), Vietnam Academy of Science and Technology (VAST), Vietnam

Vo Nguyen Dang Khoa obtained his PhD from the University of Reims Champagne-Ardenne and is currently working at the Institute of Applied Materials Science, Vietnam Academy of Science and Technology. His research focuses on the synthesis, characterization and catalytic evaluation of nanoparticles. The primary objective of his work is to elucidate the mechanism of action of natural polysaccharide and nannoparticles under irradiation for enviromental applications. Email: vndkhoa@iams.vast.vn. ORCID:  https://orcid.org/0000-0002-5693-6022

Chi Nhan Ha Thuc, University of Science, VNU-HCM, Vietnam

Corresponding author: Ha Thuc Chi Nhan obtained his Ph.D. in Polymer and Composite Materials, University of Savoie, Chambéry City, France, 2008. And recently working as the Associate Professor at Faculty of Materials Science & Technology Faculty, University of Science – National University of HoChiMinh City, 2017. His main researches focus on Synthesis and elaboration of composite and nanocomposite based on polymer and natural fillers; Synthesis and elaboration of biodegradable/ biocompatible or antibacterial materials – Application in packaging and biomedical field; Study on the adsorption of heavy metals and organic pollutants by nano materials – Application for water treatment domain; and Polymer masterbatch for plastic additives field. Email: htcnhan@hcmus.edu.vn. ORCID:  https://orcid.org/0000-0001-7003-7456

Tài liệu tham khảo

S. M. Amaraweera, and C. Gunathilake, “Development of Starch-Based Materials Using Current Modification Techniques and Their Applications: A Review,” Molecules, vol. 26, no. 22, Nov 15, 2021. DOI: https://doi.org/10.3390/molecules26226880

A. M. Nafchi, M. Moradpour, and M. Saeidi, “Thermoplastic starches: Properties, challenges, and prospects,” Starch-starke, vol. 65, pp. 61-72, 2013. DOI: https://doi.org/10.1002/star.201200201

A. Dong, J. Xie, W. Wang, L. Yu, Q. Liu, and Y. Yin, "A novel method for amino starch preparation and its adsorption for Cu(II) and Cr(VI)," Journal of Hazardous Materials, vol. 181, no. 1, pp. 448-454, 2010. DOI: https://doi.org/10.1016/j.jhazmat.2010.05.031

Zhu, H. Chen, S. Luo, and Y. Chao, "Adsorption mechanism of hydrogels for heavy metal and organics dyes removal: A short review, Journal of Agriculture and Food Resaerch, vol. 12, pp. 1-5, 2023. DOI: https://doi.org/10.1016/j.jafr.2023.100552

A. Bashir, T. Manzoor, L. A. Malik, A. Qureashi, and A. H. Pandith, "Enhanced and Selective Adsorption of Zn(II), Pb(II), Cd(II), and Hg(II) Ions by a Dumbbell- and Flower-Shaped Potato Starch Phosphate Polymer: A Combined Experimental and DFT Calculation Study," ACS Omega, vol. 5, no. 10, pp. 4853-4867, 2020. DOI: https://doi.org/10.1021/acsomega.9b03607

L. M. Fonseca, J. R. Gonçalves, and S. L. M. El Halal, “Oxidation of potato starch with different sodium hypochlorite concentrations and its effect on biodegradable films,” LWT - Food Science and Technology, vol. 60, no. 2, Part 1, pp. 714-720, 2015. DOI: https://doi.org/10.1016/j.lwt.2014.10.052

X. Yi, S. Zhang, and B. Ju, “Preparation of water-soluble oxidized starch with high carbonyl content by sodium hypochlorite,” Starch - Stärke, vol. 66, 2014. DOI: https://doi.org/10.1002/star.201300037

N. Masina, Y. E. Choonara, and P. Kumar, “A review of the chemical modification techniques of starch,” Carbohydrate Polymers, vol. 157, pp. 1226-1236, 2017. DOI: https://doi.org/10.1016/j.carbpol.2016.09.094

G. Sarma, S. Gupta, and K. Bhattacharyya, “Adsorption of Crystal violet on raw and acid-treated montmorillonite, K10, in aqueous suspension,” Journal of Environmental Management, vol. 171, pp. 1-10, 2016. DOI: https://doi.org/10.1016/j.jenvman.2016.01.038

W. Wang, J. Ni, L. Chen, Z. Ai, Y. Zhao, and S. Song, "Synthesis of carboxymethyl cellulose-chitosan-montmorillonite nanosheets composite hydrogel for dye effluent remediation," International Journal of Biological Macromolecules, vol. 165, pp. 1-10, 2020. DOI: https://doi.org/10.1016/j.ijbiomac.2020.09.154

A. Loqman, B. El Bali, J. Lu¨tzenkirchen, P. Weidler, and A. Kherbeche, "Adsorptive removal of crystal violet dye by a local clay and process optimization by response surface methodology," Applied Water Science, 2016. DOI: https://doi.org/10.1007/s13201-016-0509-x

S. Xie et al., "Application of clay minerals as adsorbents for removing heavy metals from the environment," Green and Smart Mining Engineering, vol. 1, no. 3, pp. 249-261, 2024. DOI: https://doi.org/10.1016/j.gsme.2024.07.002

G. R. Rao, I. Srikanth, and K. L. Reddy, “Effect of organo-modified montmorillonite nanoclay on mechanical, thermal and ablation behavior of carbon fiber/phenolic resin composites,” Defence Technology, vol. 17, no. 3, pp. 812-820, 2021. DOI: https://doi.org/10.1016/j.dt.2020.05.012

N. V. Hung, L. H. Tam, V. N. Dang Khoa, and H. T. Chi Nhan, “Synthesis of starch modified montmorillonite as an effective adsorbent for Pb (II) removal from water,” Vietnam Journal of Science and Technology, vol. 57, pp. 94, 2019. DOI: https://doi.org/10.15625/2525-2518/57/3A/13952

Y. Zuo, W. Liu, J. Xiao et al., “Preparation and characterization of dialdehyde starch by one-step acid hydrolysis and oxidation,” International Journal of Biological Macromolecules, vol. 103, pp. 1257-1264, 2017. DOI: https://doi.org/10.1016/j.ijbiomac.2017.05.188

N. V. Hung, L. H. Tam, C. V. Hai, V. N. D. Khoa, and H. T. C. Nhan, “The starch modified montmorillonite for the removal of Pb(II), Cd(II) and Ni(II) ions from aqueous solutions,” Arabian Journal of Chemistry, vol. 13, no. 9, pp. 7212-7223, 2020. DOI: https://doi.org/10.1016/j.arabjc.2020.08.003

N. V. Hung, L. H. Tam, V. N. D. Khoa, and H. T. C. Nhan, “Cassava starch modified montmorillonite - an efficient material for removal of crystal violet dye from contaminated aqueous solution,” Research Journal of Chemistry and Environment, 2024.

Tải xuống

Đã Xuất bản

2024-12-28

Cách trích dẫn

[1]
Van Hung Nguyen, Dang Khoa Vo Nguyen, và Chi Nhan Ha Thuc, “Synthesis and Characterization of Oxidized Starch-Montmorillonite Composite for Efficient Removal of Crystal Violet Dye from Aqueous Solutions”, JTE, vol 19, số p.h Special Issue 05, tr 92–100, tháng 12 2024.

Số

T. 19 S. Special Issue 05 (2024)

Chuyên mục

Bài báo khoa học

Categories

Giấy phép

Bản quyền (c) 2024 Tạp chí Khoa học Giáo dục Kỹ Thuật

Giấy phép Creative Commons

Tác phẩm này được cấp phép theo Giấy phép quốc tế Creative Commons Attribution-NonCommercial 4.0 .

Bản quyền thuộc về JTE.

Crossref
Scopus
Google Scholar
Europe PMC

Các bài báo được đọc nhiều nhất của cùng tác giả