Review on Hydrogenation of Biomass Derived 5-Hydroxymethylfurfural to 2,5-Dimethylfuran

Các tác giả

Email tác giả liên hệ:

luphuoc76@gmail.com

DOI:

https://doi.org/10.54644/jte.2025.1869

Từ khóa:

2,5-dimethylfuran, 5-hydroxymethylfurfural, Hydrodeoxygenation, Hydrogenolysis, Biomass

Tóm tắt

Biofuels play a crucial role as potential substitutes for fossil fuels in the transition towards sustainable energy systems. Among these bioenergy carriers, 2,5-dimethylfuran (2,5-DMF) has emerged as a promising alternative fuel due to its favorable physicochemical properties. Biomass resources such as cellulose and hemicellulose the two principal structural components of lignocellulosic biomass can be converted via hydrolysis and pyrolysis into a range of biomass-derived fuels. This conversion pathway is of particular significance for the sustainable utilization of renewable resources in support of green and circular economies. Recent advances in the catalytic transformation of 5-hydroxymethylfurfural (5-HMF) from biomass into 2,5-DMF via selective dehydration are reviewed, with a focus on reaction mechanisms, single-metal catalysts (Ru-, Pt-, Cu-, and Ni-based), bimetallic catalysts, and various solvent systems, including tetrahydrofuran, alcohols, acids, water, and biphasic systems. Notably, 2,5-DMF derived from biomass exhibits a high energy density, elevated octane number, immiscibility with water yet high miscibility with gasoline, along with advantages such as high productivity, low initial capital cost, and the capacity to valorize agricultural by-products.

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Tiểu sử Tác giả

Hue Phuoc Lu, Ho Chi Minh City University of Transport, Vietnam

Hue Phuoc Lu. Born in 1994, is from An Giang province, Vietnam. He graduated with a degree in mechanical engineering from the University of Transport Ho Chi Minh City in 2017. He is pursuing a master's degree in Automotive Engineering at the University of Transport Ho Chi Minh City and is currently researching biofuels applied to internal combustion engines to reduce harmful emissions into the environment.

Phone: 0909103795. Email: luphuoc76@gmail.com. ORCID:  https://orcid.org/0009-0001-5280-7346

Tài liệu tham khảo

D. B. Sulis et al., “Advances in lignocellulosic feedstocks for bioenergy and bioproducts,” Nature Communications, vol. 16, no. 1244, pp. 1-13, 2025, doi: https://doi.org/10.1038/s41467-025-56472-y DOI: https://doi.org/10.1038/s41467-025-56472-y

D. Chakraborty and A. Bhaumik, “Sustainable synthesis of 2,5-Dimethylfuran (DMF): A next-generation biofuel,” ChemCatChem, vol. 17, pp. 1-10, 2025, doi: doi.org/10.1002/cctc.202500563. DOI: https://doi.org/10.1002/cctc.202500563

J. He, J. Peng, R. Ling, and J. Wang, “Recent progress on the production of liquid fuel 2,5-dimethylfuran via chemoselective hydrogenolysis biomass-derived 5-hydroxymethylfurfural,” Catalysts, vol. 15, no. 1, pp. 31, 2025, doi: https://doi.org/10.3390/catal15010031. DOI: https://doi.org/10.3390/catal15010031

A. T. Hoang et al., “Synthesis pathway and combustion mechanism of a sustainable biofuel 2,5-Dimethylfuran: Progress and prospective,” Fuel, vol. 286, no. 2, 2021, doi: https://doi.org/10.1016/j.fuel.2020.119337. DOI: https://doi.org/10.1016/j.fuel.2020.119337

M. L. Testa, A. M. Venezia, and M. Russo, “Technologies to convert lignocellulosic biomass to fuel components such as DMF,” In Sustainable and Green Catalytic Processes for Renewable Fuel Production with Net-Zero Emissions, Elsevier: Amsterdam, The Netherlands, pp. 287–317, 2025, doi: http://dx.doi.org/10.1016/B978-0-443-21899-6.00012-4. DOI: https://doi.org/10.1016/B978-0-443-21899-6.00012-4

M. Russo and M. L. Testa, “Paving the way for the clean and feasible production of 2,5-dimethylfuran,” Sustain. Chem., vol. 5, no. 4, pp. 330-333, 2024, doi: https://doi.org/10.3390/suschem5040024 DOI: https://doi.org/10.3390/suschem5040024

J. Xia et al., “Hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over a modified coal-hydrotalcite catalyst,” Front. Chem., vol. 10, pp. 1-12, 2022, doi: https://doi.org/10.3389/fchem.2022.907649 DOI: https://doi.org/10.3389/fchem.2022.907649

D. K. Lee et al., “The impact of 5-hydroxymethylfurfural (HMF)-metal interactions on the electrochemical reduction pathways of HMF on various metal electrodes,” ChemSusChem, vol. 14, pp. 1– 11, 2021, doi: https://doi.org/10.1002/cssc.202101037 DOI: https://doi.org/10.1002/cssc.202101037

N. A. Endot, R. Junid, and M. S. S. Jamil, “Insight into biomass upgrading: A review on hydrogenation of 5 hydroxymethylfurfural (HMF) to 2,5 dimethylfuran (DMF),” Molecules vol. 26, no. 22, pp. 6848, 2021, doi: https://doi.org/10.3390/molecules26226848. DOI: https://doi.org/10.3390/molecules26226848

Y. Duan et al., “A comprehensive review on metal catalysts for the production of cyclopentanone derivatives from furfural and HMF,” Molecules, vol. 28, no. 14, pp. 5397, 2023, doi: https://doi.org/10.3390/molecules28145397 DOI: https://doi.org/10.3390/molecules28145397

C. Su et al., “Supporting nano catalysts for the selective hydrogenation of biomass-derived compounds,” ChemSusChem, vol. 17, no. 20, pp. 1-24, 2024, doi: https://doi.org/10.1002/cssc.202400602 DOI: https://doi.org/10.1002/cssc.202400602

H. Qu et al., “Efficient hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over Ni-C3N4 catalysts with ultra-low Ni loading,” Chinese Journal of Catalysis, vol. 60, pp. 253-261, 2024, doi: https://doi.org/10.1016/S1872-2067(24)60017-3 DOI: https://doi.org/10.1016/S1872-2067(24)60017-3

Z. Dong, Y. Zhang, and H. Xia, “Selective hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran with high yield over bimetallic Ru–Co/AC catalysts,” RSC Adv., vol. 14, pp. 14982-14991, 2024, doi: https://doi.org/10.1039/D4RA02054E DOI: https://doi.org/10.1039/D4RA02054E

Y. Xin et al., “Selective 5-Hydroxymethylfurfural hydrogenolysis to 2,5-Dimethylfuran over bimetallic Pt-FeOx/AC catalysts,” Catalysts, vol. 11, no. 8, pp. 915, 2021, doi: https://doi.org/10.3390/catal11080915 DOI: https://doi.org/10.3390/catal11080915

W. Han et al., “Efficient hydrogenolysis of 5-hydroxymethylfurfural to produce 2,5-dimethylfuran using unsupported nickel–molybdenum nitride catalysts,” New J. Chem., 2025, doi: https://doi.org/10.1039/D5NJ02151K DOI: https://doi.org/10.1039/D5NJ02151K

A. B. Raut et al., “Hydrogenolysis of biomass-berived 5-Hydroxymethylfurfural to produce 2,5-Dimethylfuran over Ru-ZrO2-MCM-41 catalyst,” Chemistry Select, vol. 4, no. 20, pp. 6080-6089, 2019, doi: https://doi.org/10.1002/slct.201901145 DOI: https://doi.org/10.1002/slct.201901145

X. Wang, Y. Liu, and X. Liang, “Hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over supported Pt–Co bimetallic catalysts under mild conditions,” Green Chem., vol. 20, pp. 2894-2902, 2018, doi: https://doi.org/10.1039/C8GC00716K DOI: https://doi.org/10.1039/C8GC00716K

P. Hao et al., “Selective Hydrogenation of 5- Hydroxymethylfurfural to 2,5- Dimethylfuran over popcorn-like nitrogen-doped carbon-confined CuCo bimetallic catalyst,” Front. Chem., vol. 10, pp. 1-9, 2022, doi: 10.3389/fchem.2022.882670 DOI: https://doi.org/10.3389/fchem.2022.882670

T. Wang et al., “Highly efficient catalytic transfer hydrogenation of 5-hydroxymethylfurfural to 2,5-dimethylfuran over CuxZnAl catalysts,” Asia-Pac J Chem Eng., vol. 17, no. 1, pp. 1-13, 2022, doi: https://doi.org/10.1002/apj.2736 DOI: https://doi.org/10.1002/apj.2736

D. Wu et al., “Dual metal−acid Pd-Br catalyst for selective hydrodeoxygenation of 5 Hydroxymethylfurfural (HMF) to 2,5-Dimethylfuran at ambient temperature,” ACS Catal., vol. 11, no. 1, pp. 19−30, 2021, doi: https://doi.org/10.1021/acscatal.0c03955. DOI: https://doi.org/10.1021/acscatal.0c03955

B. Hu et al., “Formic acid-assisted selective hydrogenolysis of 5- Hydroxymethylfurfural to 2,5-Dimethylfuran over bifunctional Pd nanoparticles supported on N-doped mesoporous carbon,” Angew Chem Int Ed Engl., vol. 60, no. 12, pp. 6807–6815, 2021. DOI: https://doi.org/10.1002/anie.202012816

Y. Yang et al., “Hydrogenolysis of 5 Hydroxymethylfurfural to 2,5-Dimethylfuran under mild conditions without any additive,” ACS Sustainable Chem. Eng., vol. 7, no. 6, pp. 5711–5716, 2019, doi: https://doi.org/10.1021/acssuschemeng.8b04937. DOI: https://doi.org/10.1021/acssuschemeng.8b04937

B. S. Solanki and C. V. Rode, “Selective hydrogenation of 5-HMF to 2,5-DMF over a magnetically recoverable non-noble metal catalyst,” Green Chemistry, vol. 21, no. 23, pp. 6390-6406, 2019, doi: 10.1039/C9GC03091C. DOI: https://doi.org/10.1039/C9GC03091C

Q. Zhang et al., “Non noble-metal copper-cobalt bimetallic catalyst for efficient catalysis of the hydrogenolysis of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran under mild conditions,” ACS Omega, vol. 6, no. 16, pp. 10910-10920, 2021. DOI: https://doi.org/10.1021/acsomega.1c00676

H. Jia et al., “Tailoring the catalytic performance of Cu/SiO2 for hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to renewable fuels,” Front. Chem., vol. 10, pp. 979353, 2022, doi: 10.3389/fchem.2022.979353. DOI: https://doi.org/10.3389/fchem.2022.979353

N. Hu et al., “Selective hydrogenation of 5-hydroxymethylfurfural to biofuel 2,5-dimethylfuran over a CuNi/ZrO2-SBA-15 catalyst,” New J. Chem.,vol. 49, pp. 11853-11861, 2025, doi: https://doi.org/10.1039/D5NJ01480H. DOI: https://doi.org/10.1039/D5NJ01480H

S. Chen et al., “Hydroconversion of 5-hydroxymethylfurfural to 2,5-dimethylfuran and 2,5-dihydroxymethyltetrahydrofuran over non-promoted Ni/SBA-15,” ChemCatChem., vol. 12, pp. 2050–2059, 2020, doi: doi.org/10.1002/cctc.201902028. DOI: https://doi.org/10.1002/cctc.201902028

J. C. Elizalde et al., “2,5-Dimethylfuran production by catalytic hydrogenation of 5-Hydroxymethylfurfural using Ni supported on Al2O3-TiO2-ZrO2 prepared by sol-gel method: the effect of hydrogen donors,” Molecules, vol. 27, no. 13, pp. 4187, 2022. DOI: https://doi.org/10.3390/molecules27134187

J. Xia et al., “Efficient and selective hydrogenation of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran over a non-noble CoNCx/NiFeO catalyst,” Catalysis Letters, vol. 152, pp. 3400–3413, 2022, doi: https://doi.org/10.1007/s10562-022-03919-2 DOI: https://doi.org/10.1007/s10562-022-03919-2

B. Chen et al., “Carbon-coated Cu-Co bimetallic nanoparticles as selective and recyclable catalysts for production of biofuel 2,5-dimethylfuran,” Appl. Catal. B Environ., vol. 200, pp. 192–199, 2017, doi: https://doi.org/10.1016/j.apcatb.2016.07.004. DOI: https://doi.org/10.1016/j.apcatb.2016.07.004

P. Priecel et al., “fast catalytic hydrogenation of 2,5-Hydroxymethylfurfural to 2,5-Dimethylfuran with ruthenium on car-bon nanotubes,” Ind. Eng. Chem. Res., vol. 57, no. 6, pp. 1991–2002, 2018, doi: https://doi.org/10.1021/acs.iecr.7b04715. DOI: https://doi.org/10.1021/acs.iecr.7b04715

A. Iriondo et al., “2,5-DMF production through hydrogenation of real and synthetic 5-HMF over transition metal catalysts supported on carriers with different nature,” Catalysis Today, vol. 279, pp. 286-295, 2017, doi:10.1016/j.cattod.2016.02.019. DOI: https://doi.org/10.1016/j.cattod.2016.02.019

F. Zhang et al., “Efficient production of the liquid fuel 2,5-dimethylfuran from 5-hydroxymethylfurfural in the absence of acid additive over bimetallic PdAu supported on graphitized carbon,” Energy & Fuels, vol. 31, no. 6, pp. 6364-6373. 2017. DOI: https://doi.org/10.1021/acs.energyfuels.7b00428

J. Luo et al., “Unraveling the surface state and composition of highly selective nanocrystalline Ni-Cu alloy catalysts for hydrodeoxygenation of HMF,” Catalysis Science & Technology, vol. 7, no. 8, pp. 1735-1743, 2017, doi: 10.1039/c6cy02647h. DOI: https://doi.org/10.1039/C6CY02647H

P. Yang et al., “Catalytic transfer hydrogenation/hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over Ni-Co/C catalyst,” Fuel, vol. 187, pp. 159-166, 2017, doi:10.1016/j.fuel.2016.09.026. DOI: https://doi.org/10.1016/j.fuel.2016.09.026

S. Srivastava, G.C. Jadeja, and J. Parikh, “Influence of supports for selective production of 2,5-dimethylfuran via bimetallic copper-cobalt catalyzed 5-hydroxymethylfurfural hydrogenolysis,” Chinese Journal of Catalysis, vol. 38, no. 4, pp. 699-709, 2017. DOI: https://doi.org/10.1016/S1872-2067(17)62789-X

Y. Yang et al., “Selective hydrodeoxygenation of 5-hydroxymethylfurfural to 2,5-dimethylfuran on Ru–MoOx/C catalysts,” RSC Advances, vol. 7, no. 27, pp. 16311-16318, 2017, doi:10.1039/C7RA00605E. DOI: https://doi.org/10.1039/C7RA00605E

R. Huang et al., “Selective hydrogenation of 5-hydroxymethylfurfural triggered bya high Lewis acidic Ni-based transition metal carbide catalyst,” Green Energy & Environment, vol. 10, no. 3, pp. 573-584, 2025, doi: https://doi.org/10.1016/j.gee.2024.05.007 DOI: https://doi.org/10.1016/j.gee.2024.05.007

H. Xia, J. Li, and M. Zhou, “Advances in Selective Hydrogenation of 5-Hydroxymethylfurfural over heterogeneous metal catalysts,” Energies, vol. 16, no. 19, pp. 6793, 2023, doi: https://doi.org/10.3390/en16196793. DOI: https://doi.org/10.3390/en16196793

P. Kashyap et al., “Ru/TiO2 catalyzed high-yield synthesis of furanic diols by 5-Hydroxymethylfurfural hydrogenation with switchable selectivity,” ChemCatChem., vol. 17, no. 2, pp. 1-12, 2025, doi: https://doi.org/10.1002/cctc.202401433. DOI: https://doi.org/10.1002/cctc.202401433

Y. Wang et al., “Efficient hydrogenation of 5-hydroxymethylfurfural using a synergistically bimetallic Ru–Ir/C catalyst,” Chem. Commun., vol. 57, pp. 1742–1745, 2021, doi: https://doi.org/10.1039/D0CC07782H. DOI: https://doi.org/10.1039/D0CC07782H

L. Wang et al., “Single-atom catalysts with metal-acid synergistic effect toward hydrodeoxygenation tandem reactions,” Chem Catalysis, vol. 3, no. 1, pp. 1-17, 2023, doi: https://doi.org/10.1016/j.checat.2022.11.022. DOI: https://doi.org/10.1016/j.checat.2022.11.022

K. Zhang et al., “Selective Hydrogenolysis of 5-Hydroxymethylfurfural into 2,5-Dimethylfuran under Mild Conditions Using Pd/MOF-808,” ACS Sustainable Chem. Eng., vol. 10, no. 31, pp. 10286–10293, 2022, doi: https://doi.org/10.1021/acssuschemeng.2c02393. DOI: https://doi.org/10.1021/acssuschemeng.2c02393

B.S. Solanki and CV. Rode, “Selective hydrogenolysis of 5-(hydroxymethyl)furfural over Pd/C catalyst to 2,5-dimethylfuran,” Journal of Saudi Chemical Society, vol. 23, no. 4, pp. 439-451, 2019, doi: https://doi.org/10.1016/j.jscs.2018.08.009. DOI: https://doi.org/10.1016/j.jscs.2018.08.009

Y. Shang et al., “Insights into the synergistic effect in Pd immobilized to MOF derived Co-CoOx@N-doped carbon for efficient selective hydrogenolysis of 5 Hydroxylmethylfurfural,” Ind. Eng. Chem. Res., vol. 59, pp. 6532−6542, 2020. DOI: https://doi.org/10.1021/acs.iecr.9b07099

S. Xiang et al., “A unique Co@CoO catalyst for hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to 2,5-dimethylfuran,” Nature Communications, vol. 13, no. 3657, pp. 1-9, 2022, doi: https://doi.org/10.1038/s41467-022-31362-9. DOI: https://doi.org/10.1038/s41467-022-31362-9

J. Wang et al., “Constructing Co@N-doped graphene shell catalyst via Mott-Schottky effect for selective hydrogenation of 5-hydroxylmethylfurfural,” Applied Catalysis B: Environmental, vol. 263, pp. 118339, 2020. DOI: https://doi.org/10.1016/j.apcatb.2019.118339

D. D. Lakshmi et al., “Selective hydrodeoxygenation of 5-hydroxymethylfurfural to 2, 5-dimethylfuran over mesoporous silica supported copper catalysts,” Materials Science for Energy Technologies, vol. 4, pp. 357-366, 2021. DOI: https://doi.org/10.1016/j.mset.2021.08.012

L. M. Esteves et al., “Effect of support on selective 5-hydroxymethylfurfural hydrogenation towards 2,5-dimethylfuran over copper catalysts,” Fuel, vol. 270, pp. 117524, 2020, doi: https://doi.org/10.1016/j.fuel.2020.117524. DOI: https://doi.org/10.1016/j.fuel.2020.117524

M. Przydacz et al., “Solvothermal hydrodeoxygenation of hydroxymethylfurfural derived from biomass towards added value chemicals on Ni/TiO2 catalysts,” J. of Supercritical Fluids, vol. 163, pp. 104827, 2020, doi: https://doi.org/10.1016/j.supflu.2020.104827. DOI: https://doi.org/10.1016/j.supflu.2020.104827

Z. Zhang et al., “Hydrothermal carbon-supported Ni catalysts for selective hydrogenation of 5-hydroxymethylfurfural toward tunable products,” J Mater Sci., vol.55, pp. 14179–14196, 2020, doi: https://doi.org/10.1007/s10853-020-05052-0. DOI: https://doi.org/10.1007/s10853-020-05052-0

Y. Li et al., “Hydrogenation and hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran via synergistic catalysis of Ni2In and acid-base sites,” Applied Surface Science, vol. 604, pp. 154579, 2022, doi: https://doi.org/10.1016/j.apsusc.2022.154579. DOI: https://doi.org/10.1016/j.apsusc.2022.154579

Z. Xia et al., “Ni–Al/CoOx-catalyzed hydrodeoxygenation of 5-hydroxymethylfurfural into 2,5-dimethylfuran at low temperatures without external hydrogen,” Green Chem., vol. 23, pp. 7763-7772, 2021, doi: https://doi.org/10.1039/D1GC02758A. DOI: https://doi.org/10.1039/D1GC02758A

N. Ma et al., “Multifunctional NiCoTi catalyst derived from layered double hydroxides for selective hydrogenation of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran,” Catal Lett., vol. 151, pp.517–525, 2021. DOI: https://doi.org/10.1007/s10562-020-03323-8

N. Chen et al., “Catalytic hydrogenolysis of hydroxymethylfurfural to highly selective 2,5- dimethylfuran over FeCoNi/h-BN catalyst,” Chemical Engineering Journal, vol. 381, pp. 122755, 2020, doi: https://doi.org/10.1016/j.cej.2019.122755. DOI: https://doi.org/10.1016/j.cej.2019.122755

S. Wang et al., “Recent advances in noble metal-based catalysts for CO oxidation,” RSC Adv., vol. 14, pp. 30566-30581, 2024, doi: https://doi.org/10.1039/D4RA05102E. DOI: https://doi.org/10.1039/D4RA05102E

K. Zhao et al., “Bimetallic catalysts as electrocatalytic cathode materials for the oxygen reduction reaction in microbial fuel cell: A review,” Green Energy & Environment, vol. 8, no. 4, pp. 1043-1070, 2023, doi: https://doi.org/10.1016/j.gee.2022.10.007. DOI: https://doi.org/10.1016/j.gee.2022.10.007

H. Lin et al., “Bimetallic nanoparticles: advances in fundamental investigations and catalytic applications,” Environ. Sci. Adv., vol. 4, pp. 33-56, 2025, doi: https://doi.org/10.1039/D4VA00241E. DOI: https://doi.org/10.1039/D4VA00241E

A. D. Talpade, M.S. Tiwari, and G.D. Yadav, “Selective hydrogenation of bio-based 5-hydroxymethyl furfural to 2,5-dimethylfuran over magnetically separable Fe-Pd/C bimetallic nanocatalyst,” Molecular Catalysis, vol. 465, pp. 1-15, 2019, doi: https://doi.org/10.1016/j.mcat.2018.12.009. DOI: https://doi.org/10.1016/j.mcat.2018.12.009

S. Umasankar et al., “Effect of copper on NiCu bimetallic catalyst supported on SBA-16 for the catalytic hydrogenation of 5-hydroxymethylfurfural to 2,5-dimethylfuran,” Biomass and Bioenergy, vol. 143, pp. 105868, 2020, doi: https://doi.org/10.1016/j.biombioe.2020.105868. DOI: https://doi.org/10.1016/j.biombioe.2020.105868

D. W. Guo et al., “Titanium silicalite-1 supported bimetallic catalysts for selective hydrogenolysis of 5-hydroxymethylfurfural to biofuel 2, 5-dimethylfuran,” Chem. Eng. J. Adv., vol. 5, pp. 100081, 2021, doi: https://doi.org/10.1016/j.ceja.2020.100081. DOI: https://doi.org/10.1016/j.ceja.2020.100081

N. Chanhom, P. Prasertpong, and N. Tippayawong, “Catalytic conversion of 5-hydroxymethylfurfural to furan derivatives 2,5-dimethylfuran,” Applied Chemical Engineering, vol. 8, no. 1, pp. 1-13, 2025, doi: http://dx.doi.org/10.59429/ace.v8i1.5581. DOI: https://doi.org/10.59429/ace.v8i1.5581

L. Tao et al., “Toward an Integrated Conversion of 5-Hydroxymethylfurfural and Ethylene for the Production of Renewable p-Xylene,” Chem., vol. 4, no. 9, pp. 2212-2227, 2018, doi: https://doi.org/10.1016/j.chempr.2018.07.007. DOI: https://doi.org/10.1016/j.chempr.2018.07.007

Y. W. Hsiao et al., “Selective hydrodeoxygenation of 5-hydroxymethylfurfural (HMF) to 2,5-dimethylfuran (DMF) over carbon supported copper catalysts using isopropyl alcohol as a hydrogen donor,” Applied Catalysis B: Environmental, vol. 317, pp. 121790, 2022, doi: https://doi.org/10.1016/j.apcatb.2022.121790. DOI: https://doi.org/10.1016/j.apcatb.2022.121790

Z. Zhang et al., “CuZnCoOx multifunctional catalyst for in situ hydrogenation of 5-hydroxymethylfurfural with ethanol as hydrogen carrier,” Journal of Catalysis, vol. 373, pp. 314–321, 2019, doi: https://doi.org/10.1016/j.jcat.2019.04.011 DOI: https://doi.org/10.1016/j.jcat.2019.04.011

J. Zhang and J. Chen, “Selective transfer hydrogenation of biomass-based furfural and 5-hydroxymethylfurfural over hydrotalcite-derived copper catalysts using methanol as hydrogen donor,” ACS Sustainable Chem. Eng., vol. 5, no. 7, pp. 5982–5993, 2017, doi: https://doi.org/10.1021/acssuschemeng.7b00778. DOI: https://doi.org/10.1021/acssuschemeng.7b00778

Z. Li et al., “5 Hydroxymethylfurfural hydrodeoxygenation coupled with watergas shift reaction for 2,5-Dimethylfuran production over Au/ZrO2 catalysts,” ACS Sustainable Chem. Eng., vol. 9, no. 18, pp. 6355−6369, 2021, doi: https://doi.org/10.1021/acssuschemeng.1c00616. DOI: https://doi.org/10.1021/acssuschemeng.1c00616

A. Martina et al., “Biobased chemicals from D Galactose: an efficient route to 5 Hydroxymethylfurfural using a Water/MIBK system in combination with an HCl/AlCl3 catalyst,” ACS Omega, vol. 9, no. 39, pp. 40378−40393, 2024, doi: https://doi.org/10.1021/acsomega.4c02242. DOI: https://doi.org/10.1021/acsomega.4c02242

H. Guo and X. Qi, “Deep eutectic solvents for synthesis of 5-hydroxymethylfurfural,” Current Opinion in Green and Sustainable Chemistry, vol. 47, pp. 100924, June 2024, doi: https://doi.org/10.1016/j.cogsc.2024.100924. DOI: https://doi.org/10.1016/j.cogsc.2024.100924

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2025-11-28

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H. P. Lu, “Review on Hydrogenation of Biomass Derived 5-Hydroxymethylfurfural to 2,5-Dimethylfuran”, JTE, vol 20, số p.h 04, tr 31–40, tháng 11 2025.

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