Hydrothermal Synthesis of Fenton Catalyst from Soybean Curd Residue Biochar for Tetracycline Degradation

Các tác giả

Email tác giả liên hệ:

datnd@hcmute.edu.vn

DOI:

https://doi.org/10.54644/jte.2024.1588

Từ khóa:

Fenton, Hydrothermal method, Pharmaceutical, Food waste, Goethite

Tóm tắt

In this study, heterogeneous catalysts were synthesized by hydrothermal method to load nano goethite to biochar derived from soybean curd residue, which served as catalysts for the heterogeneous degradation of tetracycline hydrochloride (TCH) in an aqueous solution. The catalytic tests using this composite material demonstrated significant TCH degradation. After 90 min of reaction, the optimum degradation of TCH in the aqueous solution was achieved. The initial pH value and TCH concentration were set at 2 and 50 mg/L, respectively, and the ambient conditions were maintained. The results showed that 0.5 g/L of catalyst and 60.0 mM H2O2 were the ideal catalyst and reagent dosages. Experimental data showed that the second-order kinetic model accurately described the degradation process than the first-order kinetic model. The study showed that biochar-loading goethite could be prepared from soybean crud residue and used for the degradation of TCH in an aqueous solution. Additionally, these results also provide a new approach for catalyst generation by the hydrothermal method that might help reduce costs and be environmentally friendly.

Tải xuống: 0

Dữ liệu tải xuống chưa có sẵn.

Tiểu sử của Tác giả

Quang Sang Huynh, Phuc Thien Long Services Trading Joint Stock Company, Ho Chi Minh City, Vietnam

Huynh Quang Sang: Huynh Quang Sang is currently pursuing a master's degree at Ho Chi Minh City  University of Technology and Education, where he is majoring in Environmental Engineering. Set to graduate in 2024, His research interests are focused on innovative and sustainable methods for wastewater treatment. His work delves deeply into the development and application of biosorbents, exploring their potential to effectively remove contaminants from water at Phuc Thien Long Services Trading Joint Stock Company, Ho Chi Minh City, Vietnam. Additionally, He is investigating the Fenton oxidation process, a powerful advanced oxidation technique, to enhance the breakdown of organic pollutants. His expertise also extends to biological processes in wastewater treatment, aiming to harness natural biological mechanisms to treat and purify water. Through his studies and research, He is committed to contributing to the advancement of environmental engineering and promoting cleaner, more sustainable water treatment solutions. Email: huynhquangsang1906@gmail.com. ORCID:  https://orcid.org/0009-0002-2601-2723

Quyen Kim Thi Doan, Ton Duc Thang University, Vietnam

Doan Thi Kim Quyen: She received her PhD from the National Central University, Taiwan (2023). She is working as a lecturer at Ton Duc Thang University. Her research remit is in conversing biomass waste into high-valued add material employed to remediate the environment, such as CO2 capture, and wastewater treatment.

Email: doanthikimquyen@tdtu.edu.vn. ORCID:  https://orcid.org/0000-0002-9307-5698

Nguyen Duy Dat, Ho Chi Minh City University of Technology and Education, Vietnam

Nguyen Duy Dat: Nguyen Duy Dat has been a dedicated lecturer and researcher at HCMUTE since 2019. His scientific contributions primarily focus on micropollutants, air pollution control, and wastewater treatment. In 2019, he earned his Ph.D. from National Central University (NCU), further solidifying his expertise in these critical environmental fields.

Email: datnd@hcmute.edu.vn. ORCID:  https://orcid.org/0000-0001-5965-2060

Tài liệu tham khảo

J. Zhang, Y. Zhao, K. Zhang, A. Zada, and D. Qi, "Sonocatalytic degradation of tetracycline hydrochloride with CoFe2O4/g-C3N4 composite," Ultrason. Sonochem., vol. 94, p. 106325, 2023. DOI: https://doi.org/10.1016/j.ultsonch.2023.106325

B. Banjoko, "Environmental pharmacology–an overview," Pharmacol therapeut, 2014. DOI: https://doi.org/10.5772/57473

C. F. Nnadozie, S. Kumari, and F. Bux, "Status of pathogens, antibiotic resistance genes and antibiotic residues in wastewater treatment systems," Rev. Environ. Sci. Biotechnol., vol. 16, pp. 491-515, 2017. DOI: https://doi.org/10.1007/s11157-017-9438-x

M. A. Ahsan et al., "Adsorptive removal of methylene blue, tetracycline and Cr (VI) from water using sulfonated tea waste," Environ. Technol. Innov., vol. 11, pp. 23-40, 2018. DOI: https://doi.org/10.1016/j.eti.2018.04.003

G. Qu et al., "Simultaneous removal of chromium (VI) and tetracycline hydrochloride from simulated wastewater by nanoscale zero-valent iron/copper–activated persulfate," Environ Sci Pollut Res Int, vol. 27, pp. 40826-40836, 2020. DOI: https://doi.org/10.1007/s11356-020-10120-8

Y. Ding, W. Zhang, C. Gu, I. Xagoraraki, and H. Li, "Determination of pharmaceuticals in biosolids using accelerated solvent extraction and liquid chromatography/tandem mass spectrometry," J. Chromatogr. A, vol. 1218, no. 1, pp. 10-16, 2011. DOI: https://doi.org/10.1016/j.chroma.2010.10.112

S. F. Pan, M. P. Zhu, J. P. Chen, Z. H. Yuan, L. B. Zhong, and Y. M. Zheng, "Separation of tetracycline from wastewater using forward osmosis process with thin film composite membrane–Implications for antibiotics recovery," Sep Purif Technol, vol. 153, pp. 76-83, 2015. DOI: https://doi.org/10.1016/j.seppur.2015.08.034

C. W. Yang, C. Liu, and B. V. Chang, "Biodegradation of amoxicillin, tetracyclines and sulfonamides in wastewater sludge," Water, vol. 12, no. 8, p. 2147, 2020. DOI: https://doi.org/10.3390/w12082147

J. He, X. Yang, B. Men, and D. Wang, "Interfacial mechanisms of heterogeneous Fenton reactions catalyzed by iron-based materials: A review," J. Environ. Sci., vol. 39, pp. 97-109, 2016. DOI: https://doi.org/10.1016/j.jes.2015.12.003

S. M. Aramyan and M. Moussavi, "Advances in Fenton and Fenton based oxidation processes for industrial effluent contaminants control-a review," Int. J. Environ. Sci. Nat. Resour, vol. 2, no. 4, pp. 1-18, 2017. DOI: https://doi.org/10.19080/IJESNR.2017.02.555594

V. S. Shende, V. B. Saptal, and B. M. Bhanage, "Recent advances utilized in the recycling of homogeneous catalysis," Chem. Rec., vol. 19, no. 9, pp. 2022-2043, 2019. DOI: https://doi.org/10.1002/tcr.201800205

H. Zhou, J. Yang, W. Cao, C. Chen, C. Jiang, and Y. Wang, "Hollow Meso-crystalline Mn-doped Fe3O4 Fenton-like catalysis for ciprofloxacin degradation: Applications in water purification on wide pH range," Appl. Surf. Sci., vol. 590, p. 153120, 2022. DOI: https://doi.org/10.1016/j.apsusc.2022.153120

J. Li et al., "Application of α-Fe2O3-based heterogeneous photo-Fenton catalyst in wastewater treatment: a review of recent advances," J. Environ. Chem. Eng., vol. 10, no. 5, p. 108329, 2022. DOI: https://doi.org/10.1016/j.jece.2022.108329

C. Wang, P. Shi, Z. Wang, R. Guo, J. You, and H. Zhang, "Efficient wastewater disinfection through FeOOH-mediated photo-Fenton reaction: A review," J. Environ. Chem. Eng., p. 111269, 2023. DOI: https://doi.org/10.1016/j.jece.2023.111269

N. Thomas, D. D. Dionysiou, and S. C. Pillai, "Heterogeneous Fenton catalysts: A review of recent advances," J. Hazard. Mater., vol. 404, p. 124082, 2021. DOI: https://doi.org/10.1016/j.jhazmat.2020.124082

G. Liu, Y. Zhang, H. Yu, R. Jin, and J. Zhou, "Acceleration of goethite-catalyzed Fenton-like oxidation of ofloxacin by biochar," J. Hazard. Mater., vol. 397, p. 122783, 2020. DOI: https://doi.org/10.1016/j.jhazmat.2020.122783

N. D. Dat, Q. S. Huynh, K. A. T. Tran, and M. L. Nguyen, "Performance of heterogeneous Fenton catalyst from solid wastes for removal of emerging contaminant in water: A potential approach to circular economy," Results Eng., vol. 18, p. 101086, 2023. DOI: https://doi.org/10.1016/j.rineng.2023.101086

T. T. Loc, N. D. Dat, and H. N. Tran, "Nano-sized hematite-assembled carbon spheres for effectively adsorbing paracetamol in water: Important role of iron," J. Chem. Eng., vol. 40, no. 12, pp. 3029-3038, 2023. DOI: https://doi.org/10.1007/s11814-021-1013-z

R. Chakraborty, K. Vilya, M. Pradhan, and A. K. Nayak, "Recent advancement of biomass-derived porous carbon based materials for energy and environmental remediation applications," J. Mater. Chem., vol. 10, no. 13, pp. 6965-7005, 2022. DOI: https://doi.org/10.1039/D1TA10269A

X. Guo et al., "Application of goethite modified biochar for tylosin removal from aqueous solution," Colloids Surf. A: Physicochem. Eng. Asp., vol. 502, pp. 81-88, 2016. DOI: https://doi.org/10.1016/j.colsurfa.2016.05.015

D. D. Sewu, H. N. Tran, G. O. Boahen, and S. H. Woo, "Facile magnetic biochar production route with new goethite nanoparticle precursor," Sci. Total Environ., vol. 717, p. 137091, 2020. DOI: https://doi.org/10.1016/j.scitotenv.2020.137091

A. Bopda et al., "Ferromagnetic biochar prepared from hydrothermally modified calcined mango seeds for Fenton-like degradation of indigo carmine," C, vol. 8, no. 4, p. 81, 2022. DOI: https://doi.org/10.3390/c8040081

L. Ndlwana et al., "Sustainable hydrothermal and solvothermal synthesis of advanced carbon materials in multidimensional applications: A review," Materials, vol. 14, no. 17, p. 5094, 2021. DOI: https://doi.org/10.3390/ma14175094

Y. X. Seow et al., "A review on biochar production from different biomass wastes by recent carbonization technologies and its sustainable applications," J. Environ. Chem. Eng., vol. 10, no. 1, p. 107017, 2022. DOI: https://doi.org/10.1016/j.jece.2021.107017

P. Arauzo, P. Maziarka, K. Schoder, J. Pfersich, F. Ronsse, and A. Kruse, "Influence of sequential HTC pre-treatment and pyrolysis on wet food-industry wastes: Optimisation toward nitrogen-rich hierarchical carbonaceous materials intended for use in energy storage solutions," Sci. Total Environ., vol. 816, p. 151648, 2022. DOI: https://doi.org/10.1016/j.scitotenv.2021.151648

N. D. Dat et al., "Composites derived from synthetic clay and carbon sphere: preparation, characterization, and application for dye decontamination," Korean J. Chem. Eng., vol. 39, no. 4, pp. 1053-1064, 2022. DOI: https://doi.org/10.1007/s11814-021-0940-z

P. T. T. Ninh, N. D. Dat, M. L. Nguyen, N. T. Dong, H. P. Chao, and H. N. Tran, "Two-stage preparation of highly mesoporous carbon for super-adsorption of paracetamol and tetracycline in water: Important contribution of pore filling and π-π interaction," Environ. Res., vol. 218, p. 114927, 2023. DOI: https://doi.org/10.1016/j.envres.2022.114927

U. J. Ahile, R. A. Wuana, A. U. Itodo, R. Sha’Ato, and R. F. Dantas, "Stability of iron chelates during photo-Fenton process: The role of pH, hydroxyl radical attack and temperature," J. Water Process Eng., vol. 36, p. 101320, 2020. DOI: https://doi.org/10.1016/j.jwpe.2020.101320

G. Bae, M. W. Chung, S. G. Ji, F. Jaouen, and C. H. Choi, "pH effect on the H2O2-induced deactivation of Fe-NC catalysts," ACS Catal., vol. 10, no. 15, pp. 8485-8495, 2020. DOI: https://doi.org/10.1021/acscatal.0c00948

Q. S. Huynh and D. D. Nguyen, "Synthesis of composite material derived from soybean curd and sludge containing Fe for removal of paracetamol by heterogeneous Fenton oxidation," J. Tech. Educ., vol. 17, no. 6, pp. 86-94, 2022. DOI: https://doi.org/10.54644/jte.73.2022.1298

S. Hussain, E. Aneggi, and D. Goi, "Catalytic activity of metals in heterogeneous Fenton-like oxidation of wastewater contaminants: a review," Environ. Chem. Lett., vol. 19, no. 3, pp. 2405-2424, 2021. DOI: https://doi.org/10.1007/s10311-021-01185-z

Z. H. Xie, H. Y. Zhou, C. S. He, Z. C. Pan, G. Yao, and B. Lai, "Synthesis, application and catalytic performance of layered double hydroxide based catalysts in advanced oxidation processes for wastewater decontamination: A review," J. Chem. Eng., vol. 414, p. 128713, 2021. DOI: https://doi.org/10.1016/j.cej.2021.128713

H. J. Mansoorian, E. Bazrafshan, A. Yari, and M. Alizadeh, "Removal of azo dyes from aqueous solution using Fenton and modified Fenton processes," Health Scope, vol. 3, no. 2, 2014. DOI: https://doi.org/10.17795/jhealthscope-15507

N. Jaafarzadeh, B. Kakavandi, A. Takdastan, R. R. Kalantary, M. Azizi, and S. Jorfi, "Powder activated carbon/Fe3O4 hybrid composite as a highly efficient heterogeneous catalyst for Fenton oxidation of tetracycline: degradation mechanism and kinetic," RSC advances, vol. 5, no. 103, pp. 84718-84728, 2015. DOI: https://doi.org/10.1039/C5RA17953J

H. Wang et al., "Sulfurized oolitic hematite as a heterogeneous Fenton-like catalyst for tetracycline antibiotic degradation," Appl. Catal. B: Environ., vol. 260, p. 118203, 2020. DOI: https://doi.org/10.1016/j.apcatb.2019.118203

B. Prélot et al., "Morphology and surface heterogeneities in synthetic goethites," J. Colloid Interface Sci., vol. 261, no. 2, pp. 244-254, 2003. DOI: https://doi.org/10.1016/S0021-9797(03)00058-4

Tải xuống

Đã Xuất bản

2024-12-28

Cách trích dẫn

[1]
Quang Sang Huynh, Quyen Kim Thi Doan, và Nguyen Duy Dat, “Hydrothermal Synthesis of Fenton Catalyst from Soybean Curd Residue Biochar for Tetracycline Degradation”, JTE, vol 19, số p.h Special Issue 05, tr 12–20, tháng 12 2024.

Số

T. 19 S. Special Issue 05 (2024)

Chuyên mục

Bài báo khoa học

Categories

Giấy phép

Bản quyền (c) 2024 Tạp chí Khoa học Giáo dục Kỹ Thuật

Giấy phép Creative Commons

Tác phẩm này được cấp phép theo Giấy phép quốc tế Creative Commons Attribution-NonCommercial 4.0 .

Bản quyền thuộc về JTE.

Crossref
Scopus
Google Scholar
Europe PMC